Publications

  1. "Catalytic Coupling of Haloolefins with Anilides" Zaitsev, V. G.; Daugulis, O.* J. Am. Chem. Soc. 2005, 127, 4156-4157.
  2. "Anilide ortho-Arylation Using C-H Activation Methodology" Daugulis, O.*; Zaitsev, V. G. Angew. Chem., Int. Ed. 2005, 44, 4046-4048.
  3. "Catalytic Coupling of C-H and C-I Bonds Using Pyridine As a Directing Group" Shabashov, D.; Daugulis, O.* Org. Lett. 2005, 7, 3657-3659.
  4. "Highly Regioselective Arylation of sp3 C-H Bonds Catalyzed by Palladium Acetate" Zaitsev, V. G.; Shabashov, D.; Daugulis, O.* J. Am. Chem. Soc. 2005, 127, 13154-13155.
  5. "Monomeric Ag(I) β-Diketiminate Complexes" Chiong, H. A.; Daugulis, O.* Organometallics 2006, 25, 4054-4057.
  6. "ortho-Arylation of Benzamides" Shabashov, D.; Daugulis, O.* Org. Lett. 2006, 8, 4947-4949.
  7. "Direct Palladium-Catalyzed ortho-Arylation of Benzylamines" Lazareva, A.; Daugulis, O.* Org. Lett. 2006, 8, 5211-5213.
  8. "Regioselective Functionalization of Unreactive C-H Bonds" Daugulis, O.*; Zaitsev, V. G.; Shabashov, D.; Pham, Q.-N.; Lazareva, A. Synlett, 2006, 15, 3382-3388. Invited account about our work at the University of Houston.
  9. "Palladium-Catalyzed Arylation of Electron-Rich Heterocycles with Aryl Chlorides" Chiong, H. A.; Daugulis, O.* Org. Lett., 2007, 9, 1449-1451.
  10. "Two Methods for Direct ortho-Arylation of Benzoic Acids" Chiong, H. A.; Pham, Q.-N.; Daugulis, O.* J. Am. Chem. Soc., 2007, 129, 9879-9884.
  11. "Palladium-Catalyzed Anilide ortho-Arylation and Subsequent One-Pot Cyclization to Phenanthridines" Shabashov, D.; Daugulis, O.* J. Org. Chem., 2007, 72, 7720-7725.
  12. "Copper-Catalyzed Arylation of Heterocycle C-H Bonds" Do, H.-Q.; Daugulis, O.* J. Am. Chem. Soc. 2007, 129, 12404-12405.
  13. "Copper-Catalyzed Arylation and Alkenylation of Polyfluoroarene C-H Bonds" Do, H.-Q.; Daugulis, O.* J. Am. Chem. Soc. 2008, 130, 1128-1129.
  14. "Carbon-Hydrogen Bond Functionalization Approach for the Synthesis of Fluorenones and ortho-Arylated Benzonitriles" Shabashov, D.; Maldonado, J. M. R.; Daugulis, O.* J. Org. Chem. 2008, 73, 7818-7821.
  15. "Direct Transition-Metal-Free Intramolecular Arylation of Phenols" Bajracharya, G.; Daugulis, O.* Org. Lett. 2008, 10, 4625-4628.
  16. "A General Method for Copper-Catalyzed Arylation of Arene C-H Bonds" Do, H.-Q.; Khan, R. K. M.; Daugulis, O.* J. Am. Chem. Soc. 2008, 130, 15185-15192
  17. "A Simple Base-Mediated Halogenation of Acidic sp2 C-H Bonds under Noncryogenic Conditions" Do, H.-Q.; Daugulis, O.* Org. Lett. 2009, 11, 421-423.
  18. "Palladium (II) Acetate-Butyldi-1-Adamantyphosphine Catalyzed Arylation of Electron-Rich Heterocycles. Preparation of 5-Phenyl-2-Isobutylthiazole" Lazareva, A.; Chiong, H. A.; Daugulis, O.* Org. Synth. 2009, 86, 105.
  19. "Palladium- and Copper-Catalyzed Arylation of Carbon-Hydrogen Bonds" Daugulis, O.*; Do, H.-Q.; Shabashov, D. Acc. Chem. Res. 2009, 42, 1074-1086. Invited review about our chemistry at UH.
  20. "Copper-Catalyzed Arene C-H Bond Cross-Coupling" Do, H.-Q.; Daugulis, O.* Chem. Commun. 2009, 6433-6435.
  21. "Direct Conversion of Carbon-Hydrogen to Carbon-Carbon Bonds by First Row Transition Metal Catalysis" Kulkarni, A. A.; Daugulis, O.* Synthesis 2009, 4087-4109. Invited review.
  22. "In Situ Generation and Trapping of Aryllithium and Arylpotassium Species by Halogen, Sulfur, and Carbon Electrophiles" Popov, I.; Do, H.-Q.; Daugulis, O.* J. Org. Chem. 2009, 74, 8309-8313.
  23. "An Aromatic Glaser-Hay Reaction" Do, H.-Q.; Daugulis, O.* J. Am. Chem. Soc. 2009, 131, 17052-17053.
  24. "Palladium and Copper Catalysis in Regioselective, Intermolecular Coupling of C-H and C-X Bonds" Daugulis, O. Topics in Current Chemistry 2010, 292, 57-84. Invited review.
  25. "Nickel, Manganese, Cobalt, and Iron-Catalyzed Deprotonative Arene Dimerization" Truong, T.; Alvarado, J.; Tran, L. D., Daugulis, O.* Org. Lett. 2010, 12, 1200-1203.
  26. "Evolution of Catalysts Directed by Genetic Algorithms in a Plug-Based Microfluidic Device Tested with Oxidation of Methane by Oxygen" Kreutz, J. E.; Shukhaev, A.; Du, W.; Druskin, S.; Daugulis, O.;* Ismagilov, R. F.* J. Am. Chem. Soc. 2010, 132, 3128-3132.
  27. "Auxiliary-Assisted Palladium-Catalyzed Arylation and Alkylation of sp2 and sp3 Carbon-Hydrogen Bonds" Shabashov, D.; Daugulis, O.* J. Am. Chem. Soc. 2010, 132, 3965-3972.
  28. "A General Method for Copper-Catalyzed Arylation of Acidic Arene C-H Bonds. Preparation of 2-Chloro-5-(3-Methylphenyl)Thiophene" Alvarado, J.; Do, H.-Q.; Daugulis, O.* Org. Synth. 2010, 87, 184-191.
  29. "Copper-Catalyzed Cyanation of Heterocycle Carbon−Hydrogen Bonds" Do, H.-Q.; Daugulis, O.* Org. Lett. 2010, 12, 2517-2519.
  30. "Iron-Catalyzed Heterocycle and Arene Deprotonative Alkylation" Tran, L. D.; Daugulis, O.* Org. Lett. 2010, 12, 4277-4279.
  31. "Palladium-Catalyzed Indole, Pyrrole, and Furan Arylation by Aryl Chlorides" Nadres, E. T.; Lazareva, A.; Daugulis, O.* J. Org. Chem. 2011, 76, 471-483.
  32. "Base-Mediated Intermolecular sp2 C-H Bond Arylation via Benzyne Intermediates" Truong, T.; Daugulis, O.* J. Am. Chem. Soc. 2011, 133, 4243-4245.
  33. "Copper-Catalyzed Arylation of 1H-Perfluoroalkanes" Popov, I.; Lindeman, S.; Daugulis, O.* J. Am. Chem. Soc. 2011, 133, 9286-9289.
  34. "Transition-Metal-Free Alkynylation of Aryl Chlorides" Truong, T.; Daugulis, O.* Org. Lett. 2011, 13, 4172-4175.
  35. "A General Method for Copper-Catalyzed Arene Cross-Dimerization" Do, H.-Q.; Daugulis, O.* J. Am. Chem. Soc. 2011, 133, 13577-13586.
  36. "Intermolecular Direct Arylation of Five-Membered Ring Heterocycles by Non-Activated Aryl Chlorides" Daugulis, O. Chem. Heterocycl. Compd. 2012, 48, 21-26. Invited review.
  37. "Heterocycle Synthesis via Direct C-H/N-H Coupling" Nadres, E. T.; Daugulis, O.* J. Am. Chem. Soc. 2012, 134, 7-10.
  38. "Nonnatural Amino Acid Synthesis by Carbon-Hydrogen Bond Functionalization Methodology" Tran, L. D.; Daugulis, O.* Angew. Chem., Int. Ed. 2012, 51, 5188-5191.
  39. "Copper-Catalyzed Homodimerization of Nitronates and Enolates under an Oxygen Atmosphere" Do, H.-Q.; Tran-Vu, H.; Daugulis, O.* Organometallics 201231, 7816-7818.
  40. "Directed Functionalization of C-H Bonds – now also meta-Selective" Truong, T.; Daugulis, O.* Angew. Chem., Int. Ed. 2012, 51, 11677-11679. Highlight.
  41. "Copper-Promoted Sulfenylation of sp2 C-H Bonds" Tran, L. D.; Popov, I.; Daugulis, O.* J. Am. Chem. Soc. 2012134, 18237-18240.
  42. "Direct Intermolecular Aniline Arylation via Benzyne Intermediates" Truong, T.; Daugulis, O.* Org. Lett. 2012, 14, 5964-5967.
  43. "Divergent Reaction Pathways for Phenol Arylation by Arynes: Synthesis of Helicenes and 2-Arylphenols" Truong, T.; Daugulis, O.* Chem. Sci. 2013, 4, 531-535.
  44. "Directed Amination of Non-Acidic Arene CH Bonds by a Copper–Silver Catalytic System" Tran, L. D.; Roane, J.; Daugulis, O.* Angew. Chem., Int. Ed. 2013, 52, 6043-6046.
  45. "Copper-Catalyzed, Directing Group-Assisted Fluorination of Arene and Heteroarene C−H Bonds" Truong, T.; Klimovica, K.; Daugulis, O.* J. Am. Chem. Soc. 2013135, 9342-9345. C&E News Perspective. 
  46. "Superhydrophobic Perfluorinated Metal-Organic Frameworks" Chen, T. -H.; Popov, I.;* Zenasni, O.; Daugulis, O.; Miljanić, O.* Chem. Commun. 2013, 49, 6846-6848.
  47. "Synthesis of Highly Branched Polyethylene Using “Sandwich” (8-p-Tolyl Naphthyl α-Diimine)Nickel(II) Catalysts" Zhang, D.; Nadres, E. T.; Brookhart, M.*; Daugulis, O.* Organometallics 201332, 5136-5143.
  48. "Scope and Limitations of Auxiliary-Assisted, Palladium-Catalyzed Arylation and Alkylation of sp2 and sp3 C-H Bonds" Nadres, E. T.; Santos, G. I. F.; Shabashov, D.; Daugulis, O.* J. Org. Chem201378, 9689-9714.
  49. "Copper-Catalyzed Carboxylation of Aryl Iodides with Carbon Dioxide" Tran-Vu, H.; Daugulis, O.* ACS Catalysis 2013, 3, 2417-2420.
  50. "Copper-Catalyzed Etherification of Arene C-H Bonds" Roane, J.; Daugulis, O.* Org. Lett. 201315, 5842-5845.
  51. "Secondary Alkene Insertion and Precision Chain-Walking: A New Route to Semicrystalline “Polyethylene” from α-Olefins by Combining Two Rare Catalytic Events" Vaidya, T.; Klimovica, K.; LaPointe, A.; Keresztes, I.; Lobkovsky, E. B.; Daugulis, O.*; Coates, G.* J. Am. Chem. Soc. 2014, 136, 7213-7216.
  52. "A General Method for Functionalized Polyaryl Synthesis via Aryne Intermediates" Truong, T.; Mesgar, M.; Le, K. K. A.; Daugulis, O.* J. Am. Chem. Soc. 2014, 136, 8568-8576.
  53. "Cobalt-Catalyzed, Aminoquinoline-Directed sp2 C-H Bond Alkenylation by Alkynes" Grigorjeva, L.; Daugulis, O.* Angew. Chem., Int. Ed. 2014, 53, 10209-10212.
  54. "Cobalt-Catalyzed, Aminoquinoline-Directed Coupling of sp2 C-H Bonds with Alkenes" Grigorjeva, L.; Daugulis, O.* Org. Lett201416, 4684-4687ACS Editors Choice for August 22.
  55. "Cobalt-Catalyzed Direct Carbonylation of Aminoquinoline Benzamides" Grigorjeva, L.; Daugulis, O.* Org. Lett. 201416, 4688-4690.
  56. "Thermally robust and porous noncovalent organic framework with high affinity for fluorocarbons and Freons" Chen, T.-H.; Popov, I.; Kaveevivitchai, W.; Chuang, Y.-C.; Chen, Y.-S.;  Daugulis, O.; Jacobson, A. J.; Miljanić, O.* Nat. Comm. 20145, 5131. PhysOrgChem Perspective. C&E News Perspective.
  57. "Living Polymerization of Ethylene and Copolymerization of Ethylene/Methyl Acrylate Using "Sandwich" Diimine Palladium Catalysts" Allen, K. E.; Campos, J.; Daugulis, O.; Brookhart, M.* ACS Catalysis 20155, 456-464.
  58. "Synthesis of Branched Ultra-High-Molecular-Weight Polyethylene Using Highly Active Neutral, Single-Component Ni(II) Catalysts" Chen, Z.; Mesgar, M.; White, P.; Daugulis, O.*; Brookhart, M.* ACS Catalysis 2015, 5, 631-636.
  59. "Macrocycle Embrace: Encapsulation of Fluoroarenes by m-​Phenylene Ethynylene Host"  Popov, I.; Chen, T.-H.; Belyakov, S.; Daugulis, O.; Wheeler, S. E.; Miljanic, O. S.* Chemistry - A European Journal 2015, 21, 2750-2754.
  60. "Cobalt-Promoted Dimerization of Aminoquinoline Benzamides" Grigorjeva, L.; Daugulis, O.* Org. Lett201517, 1204-1207.
  61. "Bidentate, Monoanionic Auxiliary-Directed Functionalization of Carbon-Hydrogen Bonds" Daugulis, O.*; Roane, J.; Tran, L. D. Acc.Chem.Res. 201548,  1053-1064. Invited review about our chemistry at UH.
  62. "Cobalt-Catalyzed, Aminoquinoline-Directed Functionalization of Phosphinic Amide sp2 C−H Bonds"  Nguyen, T. T.; Grigorjeva, L.; Daugulis, O.* ACS Catalysis 2016, 6, 551-554.
  63. "A Career in Catalysis: Maurice Brookhart"  Daugulis, O.;  MacArthur, A. H. R.*; Rix, F. C.; Templeton, J. L. ACS Catalysis 2016, 6, 1518-1532. Account about carrer of Prof. M. Brookhart.
  64. "A General Method for Aminoquinoline-Directed, Copper-Catalyzed sp2 CH Bond Amination " Roane, J.; Daugulis, O.* J. Am. Chem. Soc. 2016, 138, 4601-4607.
  65. "Synthesis of Branched Polyethylene with “Half-Sandwich” Pyridine-imine Nickel Complexes" Chen, Z.; Allen, K.; White, P.; Daugulis, O.*; Brookhart, M.* Organometallics 2016, 35, 1756-1760.
  66. "Silylaryl Halides Can Replace Triflates as Aryne Precursors" Mesgar, M.; Daugulis, O.* Org. Lett.2016, 18, 3910–3913.
  67. "Synthesis and Properties of “ Sandwich ” Diimine-Coinage Metal Ethylene Complexes" Klimovica, K.; Kirschbaum, K.; Daugulis, O.* Organometallics 2016, 35, 2938−2943.
  68. "Mechanistic Studies of Pd(II)-Catalyzed Copolymerization of Ethylene and Vinylalkoxysilanes: Evidence for a β‑Silyl Elimination Chain Transfer Mechanism" Chen, Z.; Liu, W.; Daugulis, O.*; Brookhart, M.*. J. Am. Chem. Soc. 2016138, 16120-16129.
  69. "Oligomerization of Ethylene Using a Diphosphine Palladium Catalyst" Bézier, D.; Daugulis, O.*; Brookhart, M.* Organometallics 201736, 443-447.
  70. "Alkene Isomerization  By “Sandwich” Diimine-Palladium Catalysts" Kocen, A.; Klimovica, K.; Brookhart, M.*; Daugulis, O.* Organometallics 2017, 36, 787–790.
  71. "Palladium-Catalyzed Pyrazole-Directed sp3 C-H Bond Arylation for the Synthesis of beta-Phenethylamines" Gulia, N.; Daugulis, O. Angew. Chem., Int. Ed. 2017, 56, 3630–3634.
  72. "Palladium-Catalyzed, Aminoquinoline-Directed Arylation of Phosphonamidate and Phosphinic Amide sp3 C-H Bonds" Nguyen, T. T.; Daugulis, O.* Chem. Commun. 2017, 53, 4609-4611.
  73. "Aminoquinoline-Directed, Cobalt-Catalyzed Carbonylation of Sulfonamide sp2 C-H Bonds" Nguyen, T. T.; Grigorjeva, L.; Daugulis, O.* Chem. Commun.  2017, 53, 5136-5138.
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